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dc.contributor.authorLessard, Carol R.en_US
dc.date.accessioned2009-07-09T17:31:08Z
dc.date.available2009-07-09T17:31:08Z
dc.date.issued1975-07-09T17:31:08Z
dc.identifier.urihttp://hdl.handle.net/10464/1727
dc.description.abstractAlthough it is generally accepted that Rydberg orbitals are very large and diffuse, and that electron promotion to a Rydberg orbital is not too different from ionization of the molecule, analysis of the two types of transitions proves otherwise. The photoelectron spectrum of the 2B2 (n) ion has very little vibrational structure attached to the origin band; on the other hand, several of the Rydberg transitions which involve the promotion of the n(bZ) electron exhibit a great deal of vibrational activity. In particular, the members of the n=3 Rydberg\ series interact with and perturb each other through pseudo-Jahn-Teller vibronic coupling. The vacuum ultraviolet spectrum contains a number of features which are difficult to explain, and two unusually sharp bands can only be identified as representing some form of electron promotion in formaldehyde.en_US
dc.language.isoengen_US
dc.publisherBrock Universityen_US
dc.subjectFormaldehyde--Spectra.en_US
dc.subjectElectron spectroscopy.en_US
dc.titleAn analysis of the photoelectron and Rydberg states of formaldehyde /|nby Carol R. Lessard. -- 260 St. Catharines [Ont.] : Dept. of Chemistry, Brock University,en_US
dc.typeElectronic Thesis or Dissertationen_US
dc.degree.nameM.Sc. Chemistryen_US
dc.degree.levelMastersen_US
dc.contributor.departmentDepartment of Chemistryen_US
dc.degree.disciplineFaculty of Mathematics and Scienceen_US
refterms.dateFOA2021-08-07T02:27:40Z


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