The near ultraviolet absorption spectrum of phosgene /
dc.contributor.author | Foo, Pang Dow. | en_US |
dc.date.accessioned | 2009-06-09T18:16:25Z | |
dc.date.available | 2009-06-09T18:16:25Z | |
dc.date.issued | 1971-06-09T18:16:25Z | |
dc.identifier.uri | http://hdl.handle.net/10464/1563 | |
dc.description.abstract | The near ultraviolet absorption of phosgene has been assigned to a * 1 1 ~.--n, A;-- Al electronic transition from vapour phase spectra recorded under conditions of high resolution and low_t~mperature. Progressions in Vi, v2' V3' V4 and V4 ha\1e been identified in the spectrum and have been analyzed in terms of vibronic transitions between a planar ground and a nonplanar excited state. A ba~rier height of 3170 cm~l:and a nona planar equilibrium angle of 32.5 were calculated for the upper state from a fit of the energy levels of a Lorentzian-guadratic potential func- ~ion to the observed levels of V 4 . ' ~he false ori- 3in, 41 0 , of the spectrum has been assigned to the band at 33,631 cm -1 . An oscillator strength of -3 1 . 1 f = 1. a x 10 has been obtained for the A - A 2 1 transition. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Brock University | en_US |
dc.subject | Phosgene. | en_US |
dc.subject | Ultraviolet spectra. | en_US |
dc.title | The near ultraviolet absorption spectrum of phosgene / | en_US |
dc.type | Electronic Thesis or Dissertation | en |
dc.degree.name | M.Sc. Chemistry | en_US |
dc.degree.level | Masters | en_US |
dc.contributor.department | Department of Chemistry | en_US |
dc.degree.discipline | Faculty of Mathematics and Science | en_US |
refterms.dateFOA | 2021-08-07T02:15:57Z |