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    Synthesis and Derivatization of Amaryllidaceae Constituents – Narciclasine and Pancratistatin

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    Author
    Lapinskaite, Ringaile
    Keyword
    Amaryllidaceae, alkaloids, narciclasine, pancratistatin
    
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    URI
    http://hdl.handle.net/10464/14607
    Abstract
    This thesis describes the synthesis and derivatization of narciclasine and pancratistatin. A detailed description is given to the total formal synthesis of pancratistatin through a reductive transposition approach and the total and semi-syntheses of 2-epi-narciclasine and its discovery as a new natural product. The last part of this work focuses on the search for a divergent approach to access C-1 narciclasine and C-1-pancratistatin derivatives from natural narciclasine. Experimental and spectral data are provided for the new compounds.
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