Abstract:
The mass spectra and fragmentation of a variety of
fluoroaromatic compounds of Group V and some selected
transition elements are discussed in some detail, aided by
data from metastable defocussed experiments. Results of
,studies on the coupling reaction using unstable organotitanium
chloride intermediate species are reported. The
preparation of some 5-substituted octafluorodibenzophospho1es
is also discussed. Rearrangements under electron bombardment
resulting in the loss of heteroatom-fluoride fragments are
discussed in the light of presently accepted mechanisms for
these processes as are rearrangements observed in compounds
involving thionophosphoryl bonds ( p=s ).
