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dc.contributor.authorSubramaniam, Chandrasekarapuram Ramaswamy.en_US
dc.date.accessioned2009-07-09T18:54:33Z
dc.date.available2009-07-09T18:54:33Z
dc.date.issued1969-07-09T18:54:33Z
dc.identifier.urihttp://hdl.handle.net/10464/2209
dc.description.abstractThe infrared and the Raman spectra of eSelF has been obtained for the first time and has been analysed to give the in-plane normal vibrational frequencies of the molecule, in the ground state. A normal co-ordinate analysis has been carried out for the molecules CSF2, CSClF and eSel 2 using a Urey-Bradley type of potential function and the elements of the [L] matrix elements, the distribution of the potential energy in Urey-Bradley space, and the displacement vector diagrams for the normal modes of vibration for these molecules, have been obtained. The bond for~e constants obtained through the normal co-ordinate analysis, have given some interesting results. The stretching force constant, Kes ' varies markedly with halogen substitution and the force constants KeF and Keel also vary with substitution.en_US
dc.language.isoengen_US
dc.publisherBrock Universityen_US
dc.subjectHalides.en_US
dc.subjectHalides--Spectra.en_US
dc.subjectCarbonyl compounds.en_US
dc.titleThe vibrational spectra and the normal coordinate analysis of thiocarbonye halides /|nby C. R. Subramaniam. -- 260 St. Catharines, Ont. : [s. n.],en_US
dc.typeElectronic Thesis or Dissertationen_US
dc.degree.nameM.Sc. Chemistryen_US
dc.degree.levelMastersen_US
dc.contributor.departmentDepartment of Chemistryen_US
dc.degree.disciplineFaculty of Mathematics and Scienceen_US


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