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Rotation-electronic interaction in the 3p-complex Rydberg state of water

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dc.contributor.author Hussain, Syed Mohammad Javed. en_US
dc.date.accessioned 2009-07-09T18:42:42Z
dc.date.available 2009-07-09T18:42:42Z
dc.date.issued 1979-07-09T18:42:42Z
dc.identifier.uri http://hdl.handle.net/10464/2038
dc.description.abstract An energy theory is formulated for the rotational energy levels in a p-complex Rydberg state of an asymmetric top molecule of symmetry C2v. The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given. en_US
dc.language.iso eng en_US
dc.publisher Brock University en_US
dc.subject Rotors. en_US
dc.subject Rotational motion. en_US
dc.subject Molecular rotation. en_US
dc.subject Water--Analysis. en_US
dc.title Rotation-electronic interaction in the 3p-complex Rydberg state of water en_US
dc.type Electronic Thesis or Dissertation en_US
dc.degree.name M.Sc. Physics en_US
dc.degree.level Masters en_US
dc.contributor.department Department of Physics en_US
dc.degree.discipline Faculty of Mathematics and Science en_US


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