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dc.contributor.authorFranklin, Teresa Anne.en_US
dc.date.accessioned2009-07-09T18:39:03Z
dc.date.available2009-07-09T18:39:03Z
dc.date.issued1978-07-09T18:39:03Z
dc.identifier.urihttp://hdl.handle.net/10464/1956
dc.description.abstractSolid complexes of pyridoxine with Mn(II) , Cd(II) and Zn(II) have been isolated, as well as compounds containing Cu(II), Ni(II), Co(III), Cd(II) and Zn(II), and pyridoxamine in various protonated forms. Infrared spectra provide evidence for protonation at the pyridine nitrogen site in the complexes, but not in the neutral vitamins and the complexes of anionic pyridoxamine. Thus the complexed vitamins are in zwitterionic forms, with chelation probably occurring through the phenolate oxygen and either the amino or the hydroxy group at the 4' position.en_US
dc.description.abstractSolid complexes of pyridoxine with Mn(II) , Cd(II) and Zn(II) have been isolated, as well as compounds containing Cu(II), Ni(II), Co(III), Cd(II) and Zn(II), and pyridoxamine in various protonated forms. Infrared spectra provide evidence for protonation at the pyridine nitrogen site in the complexes, but not in the neutral vitamins and the complexes of anionic pyridoxamine. Thus the complexed vitamins are in zwitterionic forms, with chelation probably occurring through the phenolate oxygen and either the amino or the hydroxy group at the 4' position.en_US
dc.language.isoengen_US
dc.publisherBrock Universityen_US
dc.subjectOrganometallic compounds.en_US
dc.subjectVitamin B6.en_US
dc.subjectPyridoxamine.en_US
dc.titleMetal complexes involving pyridoxine and pyridoxamineen_US
dc.typeElectronic Thesis or Dissertationen_US
dc.degree.nameM.Sc. Chemistryen_US
dc.degree.levelMastersen_US
dc.contributor.departmentDepartment of Chemistryen_US
dc.degree.disciplineFaculty of Mathematics and Scienceen_US


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