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Fast atom bombardment mass spectrometry of the coordination complexes of the ligand 5, 5, 7, 12, 12, 14- hexamenthyl-1, 4, 8, 11-tetraazacycloteradecane

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dc.contributor.author MacLaurin, Cindy Lee. en_US
dc.date.accessioned 2009-07-09T17:35:29Z
dc.date.available 2009-07-09T17:35:29Z
dc.date.issued 1985-07-09T17:35:29Z
dc.identifier.uri http://hdl.handle.net/10464/1880
dc.description.abstract A number of metal complexes containing the ligand 5,5,7,12,12,14-hexamethyl-l,4,8,11-tetra-azatetradecane were synthesized and analyzed using electron impact (EI) and fast atom bombardment (FAB). The FAB mass spectra were obtained in positive and negative ion mode. FAB in the positive ion mode proved to be the most successful technique for the identification of these compounds. In the majority of cases the spectra obtained using positive ion FAB were structurally informative, although not all showed molecular (M+) or quasimolecular ([M+H]+) ions. The fragmentations observed were characteristic of the ligands, and were interpreted based on the chemistry of these compounds. en_US
dc.language.iso eng en_US
dc.publisher Brock University en_US
dc.subject Mass spectrometry. en_US
dc.subject Ligands. en_US
dc.subject Coordination compounds. en_US
dc.title Fast atom bombardment mass spectrometry of the coordination complexes of the ligand 5, 5, 7, 12, 12, 14- hexamenthyl-1, 4, 8, 11-tetraazacycloteradecane en_US
dc.type Electronic Thesis or Dissertation en_US
dc.degree.name M.Sc. Chemistry en_US
dc.degree.level Masters en_US
dc.contributor.department Department of Chemistry en_US
dc.degree.discipline Faculty of Mathematics and Science en_US


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