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dc.contributor.authorMacLaurin, Cindy Lee.en_US
dc.date.accessioned2009-07-09T17:35:29Z
dc.date.available2009-07-09T17:35:29Z
dc.date.issued1985-07-09T17:35:29Z
dc.identifier.urihttp://hdl.handle.net/10464/1880
dc.description.abstractA number of metal complexes containing the ligand 5,5,7,12,12,14-hexamethyl-l,4,8,11-tetra-azatetradecane were synthesized and analyzed using electron impact (EI) and fast atom bombardment (FAB). The FAB mass spectra were obtained in positive and negative ion mode. FAB in the positive ion mode proved to be the most successful technique for the identification of these compounds. In the majority of cases the spectra obtained using positive ion FAB were structurally informative, although not all showed molecular (M+) or quasimolecular ([M+H]+) ions. The fragmentations observed were characteristic of the ligands, and were interpreted based on the chemistry of these compounds.en_US
dc.language.isoengen_US
dc.publisherBrock Universityen_US
dc.subjectMass spectrometry.en_US
dc.subjectLigands.en_US
dc.subjectCoordination compounds.en_US
dc.titleFast atom bombardment mass spectrometry of the coordination complexes of the ligand 5, 5, 7, 12, 12, 14- hexamenthyl-1, 4, 8, 11-tetraazacycloteradecaneen_US
dc.typeElectronic Thesis or Dissertationen_US
dc.degree.nameM.Sc. Chemistryen_US
dc.degree.levelMastersen_US
dc.contributor.departmentDepartment of Chemistryen_US
dc.degree.disciplineFaculty of Mathematics and Scienceen_US


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