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Comparative electron impact and fast atom bombardment mass spectrometric studies of some HMPA adducts of phenyltin and phenyllead halides and studies of strong hydrogen bonding by FAB-MS

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dc.contributor.author Mondal, Humayun. en_US
dc.date.accessioned 2009-07-09T17:34:28Z
dc.date.available 2009-07-09T17:34:28Z
dc.date.issued 1984-07-09T17:34:28Z
dc.identifier.uri http://hdl.handle.net/10464/1804
dc.description.abstract The fragmentation patterns and mass spectra of some phenyl tin and -lead halide adducts with hexamethylphosphoramide are compared by subjecting them t~ electron impact and fast atom bombardment ionization in a mass spectrometer. This comparison is restricted to the metal-containing ions. Ligand-exchange mechanisms of some of the metal-containing species are explored by FAB-MS. Several moisturesensitive organo-metallics and H-bonded systems have been examined by FAB for attempted characterization, but without any success. Scavenging and trapping of water molecules by complex aggregates in solutions of quaternary ammonium fluorides and hydroxides are investigated by FAB to complement previous NMR-studies. en_US
dc.language.iso eng en_US
dc.publisher Brock University en_US
dc.subject Mass spectrometry. en_US
dc.subject Halides. en_US
dc.subject Hydrogen bonding. en_US
dc.subject Ionization. en_US
dc.title Comparative electron impact and fast atom bombardment mass spectrometric studies of some HMPA adducts of phenyltin and phenyllead halides and studies of strong hydrogen bonding by FAB-MS en_US
dc.type Electronic Thesis or Dissertation en_US
dc.degree.name M.Sc. Chemistry en_US
dc.degree.level Masters en_US
dc.contributor.department Department of Chemistry en_US
dc.degree.discipline Faculty of Mathematics and Science en_US


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