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Kinetic studies of the effect of organic sulphides on the oxidation of other sulphides /

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dc.contributor.author Aryitey, George Tetteh Magnus. en_US
dc.date.accessioned 2009-06-04T14:09:06Z
dc.date.available 2009-06-04T14:09:06Z
dc.date.issued 1984-06-04T14:09:06Z
dc.identifier.uri http://hdl.handle.net/10464/1507
dc.description.abstract The rates of oxidation of three Organic sulphides viz. methyl phenyl sulphide, (P), p -me thoxyphenyl methyl sulphide (M) and methyl p-nitrophenyl sulphide (N). have been obtained in ethanol using MoO-(acac)- as catalyst and Bu OOH as the oxidizing agent. A Hammett plot gave a rho value of -2.1 and the activation energies for the oxidation of P, M and N were estimated to be 63.60, 40.12 and 197.46 Kj mol respectively. The effect of organic sulphide on the oxidation of another sulphide was also ascertained. Positive and negative deviations were observed from the expected slope. en_US
dc.language.iso eng en_US
dc.publisher Brock University en_US
dc.subject Chemical kinetics. en_US
dc.subject Sulfides. en_US
dc.subject Oxidation. en_US
dc.title Kinetic studies of the effect of organic sulphides on the oxidation of other sulphides / en_US
dc.type Electronic Thesis or Dissertation en_US
dc.degree.name M.Sc. Chemistry en_US
dc.degree.level Masters en_US
dc.contributor.department Department of Chemistry en_US
dc.degree.discipline Faculty of Mathematics and Science en_US


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