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FT-IR and MAS NMR analysis of montmorillonite K10 supported MF2 reagents and their activity as catalysis /

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dc.contributor.author Asseid, Fathi M. en_US
dc.date.accessioned 2009-05-21T13:25:14Z
dc.date.available 2009-05-21T13:25:14Z
dc.date.issued 1991-05-21T13:25:14Z
dc.identifier.uri http://hdl.handle.net/10464/1274
dc.description.abstract ZnF2, CdF2, and CUF2 have been adsorbed onto the surface of montmorillonite K10, and the infrared and 19F, 27 AI, and 29Si MAS NMR spectra of the reagents over a range of loadings have been obtained. CUF2 was observed to attack the Si02 layer and form the complex CuSiF6, Zn F2 tends to attack the aluminium oxide layer, in which Zn isomorphously replaces AI, and forms AIF3 and AIF4 - complexes. All the spectroscopic evidence ruled out the formation of any AI-F and/or Si-F free species as CdF2 is adsorbed on the surface of montmorillonite K10. The reactivity of MF2-K10 reagents towards Friedel-Crafts benzylation of benzene with benzyl chloride varied from one reagent to another. ZnF2-K10 was observed to be the most reactive and CUF2 was the least reactive. en_US
dc.language.iso eng en_US
dc.publisher Brock University en_US
dc.subject Chemical tests and reagents. en_US
dc.subject Catalysis. en_US
dc.subject Montmorillonite. en_US
dc.subject Nuclear magnetic resonance. en_US
dc.subject Metallic oxides. en_US
dc.title FT-IR and MAS NMR analysis of montmorillonite K10 supported MF2 reagents and their activity as catalysis / en_US
dc.type Electronic Thesis or Dissertation en_US
dc.degree.name M.Sc. Chemistry en_US
dc.degree.level Masters en_US
dc.contributor.department Department of Chemistry en_US
dc.degree.discipline Faculty of Mathematics and Science en_US


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