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dc.contributor.authorAsseid, Fathi M.en_US
dc.date.accessioned2009-05-21T13:25:14Z
dc.date.available2009-05-21T13:25:14Z
dc.date.issued1991-05-21T13:25:14Z
dc.identifier.urihttp://hdl.handle.net/10464/1274
dc.description.abstractZnF2, CdF2, and CUF2 have been adsorbed onto the surface of montmorillonite K10, and the infrared and 19F, 27 AI, and 29Si MAS NMR spectra of the reagents over a range of loadings have been obtained. CUF2 was observed to attack the Si02 layer and form the complex CuSiF6, Zn F2 tends to attack the aluminium oxide layer, in which Zn isomorphously replaces AI, and forms AIF3 and AIF4 - complexes. All the spectroscopic evidence ruled out the formation of any AI-F and/or Si-F free species as CdF2 is adsorbed on the surface of montmorillonite K10. The reactivity of MF2-K10 reagents towards Friedel-Crafts benzylation of benzene with benzyl chloride varied from one reagent to another. ZnF2-K10 was observed to be the most reactive and CUF2 was the least reactive.en_US
dc.language.isoengen_US
dc.publisherBrock Universityen_US
dc.subjectChemical tests and reagents.en_US
dc.subjectCatalysis.en_US
dc.subjectMontmorillonite.en_US
dc.subjectNuclear magnetic resonance.en_US
dc.subjectMetallic oxides.en_US
dc.titleFT-IR and MAS NMR analysis of montmorillonite K10 supported MF2 reagents and their activity as catalysis /en_US
dc.typeElectronic Thesis or Dissertationen_US
dc.degree.nameM.Sc. Chemistryen_US
dc.degree.levelMastersen_US
dc.contributor.departmentDepartment of Chemistryen_US
dc.degree.disciplineFaculty of Mathematics and Scienceen_US


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